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Title: トモダチ...その名はＮ！/Tomodachi... sono na wa N!.
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Finally, the mysterious youth N meets Satoshi and his friends! N and Satoshi immediately take an interest in each other, but as soon as N hears Satoshi dreams of becoming a Pokémon Master, his expression changes completely! And then the ominous shadow aboard the ship...

Summary:
Satoshi and his friends have left Kanoko Town by ship. They're headed towards the 'White Ruins', a place connected to Reshiram, a Pokémon called legendary. En route to Hiogi City, the group meet a mysterious young man named N, who claims he can hear the voices coming from Pokémon's hearts. Instinctively and at an extremely rapid pace, N starts talking about how the relationship between Pokémon and humans should be, referring to Pokémon as 'friends', making everyone do a double-take.

Then, N makes it very clear he hates the idea of making Pokémon battle. But then suddenly, the Rocket Gang attacks! Pikachu gets in a spot as it's hit by Morobareru's Stun Spore! But in the spur of the moment, N calls on the 'Caring Pokémon' Mamanbou! And then...!?

Voice cast:
Rica Matsumoto: Satoshi
Ikue Ohtani: Pikachu
Mamoru Miyano: Dent
Aoi Yuki: Iris
Minami Tsuda: Kibago
Megumi Hayashibara: Musashi
Shinichiro Miki: Kojiro
Inuko Inuyama: Nyarth
Chinami Nishimura: Kenhallow
Kiyotaka Furushima: Doryuzu
Chiaki Takahashi: Pururill
Yuichi Nakamura: N
Unsho Ishizuka: Narration

Rather interesting episode (yay for the Rocket Gang!), and curious to see how the whole story with N will unfold. I can't say I'm a real fan of him though, both ingame and in the series.