BioBlaine is the Gym Leader of the Gym on Cinnabar Island. When Cinnabar island started to become overcroweded with tourists he decided to open a hotel near the volcano on the island. Whilst running the hotel, Blaine disguised himself using a wig and sunglasses. Blaine kept a secret battle field inside the Volcano where he battled Ash for the Volcano Badge using his Fire-type Pokémon.
Blaine used his Ninetales in a battle against Ash's Squirtle. After one flamethrower, Blaine managed to defeat Ash's Squirtle.
Rhydon was the second. Pokémon Blaine used in his first battle against Ash. Rhydon scored the victory over Ash's Charizard after it flew away and refused to battle. However, Ash decided to use Pikachu who used Rhydon's horn as a conductor when using Thunderbolt against it.
Blaine lets Magmar live in the Volcano near his hotel on Cinnabar Island. Blaine calls upon Magmar to battle Ash's Pikachu which it defeated when Ash quit after Magmar hit Pikachu with a fire blast. When Jessie, James and Meowth attacked the volcano, Magmar help move rocks to stop the flow of Lava. [View More]