The episode began with the crew saying 'PokéMorning!' to everyone as they wiggled around like they were using a hula hoop. Golgo quickly changes the topic of conversation to the Pokémon Library vote.


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The 4th Pokémon Library vote was Baba vs Shoko-tan. Baba chose Rival Showdown! Getting Windie!(ライバル対決！ウインディをゲットかも！) while Shoko-tan chose Attack! The Stray Manyula!!(襲撃！はぐれマニューラ!!) from the Advanced Generation series. Viewers could vote for their favourite episode on the official Pokémon Smash website until midnight on March 14th, 2011. Baba won the vote with 19,453 votes vs Shoko-tan's 18,192 votes.

Since Baba won the forth Pokémon Library vote, Rival Showdown! Getting Windie!(ライバル対決！ウインディをゲットかも！) from the Advanced Generation series was this weeks repeat episode. The theme for the episode this week was 'Getting Stronger because of Rivals'(ライバルがいるから強くなれる！). A full summary for that episode is available in the episode guide.　Professor Red then did his 'OK! Pokémon Library!' go-to line.

After the Pokémon Library episode, the 5th Pokémon Library vote was announced. Both episodes feature Unown. Yamamoto chose Address Unown! (ふしぎのくにのアンノーン！) while Professor Red chose Journey to the Unown!. Viewers have until midnight on April 11th, 2011 to vote for their favorite on the official Pokémon Smash website.

The Internation Division girls then showed up and Golgo introduced the Pokémon Caravan Quiz. The announcer quickly explained the quiz. Golgo then explained that to help promote the upcoming 14th movies Victini and the Light Hero - Reshiram / Victini and the Dark Hero - Zekrom (ビクティニと白き英雄レシラム / ビクティニと黒き英雄ゼクロム), the Pokémon Caravan Quiz would feature elements based on the movies and Victini.

Professor Red then brought out two pictures. One was a standard stock photo of the entire Pokémon Smash cast. The other one had multiple changes which he asked the cast members to identify. There are 5 changes. How many can you identify?


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Below are changes to the photo :

Changes	Answer
Pokémon Smash Cast Photo Changes	1. Akiyama in the front row was changed to him having his original Pokémon Sunday uniform. 2. Golgo's face was changed to a picture of him from 20 years ago. 3. Shoko-tan's face was changed to a drawing of Yamamoto's mom Tokiko by Akiyama. 4. Misaki's face was changed to Yamamoto's face. 5. Yamamoto's face was changed into a Burdock (ゴボウ). Spoiler: Click to show!

The show then switched to the VTR of the Pokémon Caravan Quiz. For this episode, the crew visited Haijimadaiyon Elementary School, Akishima City, Tokyo (東京都　昭島市立　拝島第四小学校). For this caravan the kids were split into a Black Team and White Team.


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The first segment of the quiz was the 'Black/White Quiz' (ブラックホワイトクイズ). The kids were separated into two teams and each person was given a black paddle and a white paddle. When questions were asked, they would raise the paddle they thought was the answer. The team that won would receive 10 points.

Below are changes to the photo :

#	Question	Answer
1	Pokémon Smash - Does P.E. stand for Pokémon Entertainment? (わたしたちがはたらいている会社P.E.の名前はポケモンエンターテイメントである)	(X) Black - P.E. Pokémon Enterprise (ポケモンエンタープライズ) Spoiler: Click to show!
2	Card Game - When playing the Pokémon Card Game, do you pick up 10 cards? (対戦のじゅんびで手札にひくのはポケモンカードゲームの１０まいである)	(X) Black - 7 Spoiler: Click to show!
3	Anime - Is the opening theme to Pocket Monsters Best Wishes called Best Wishes!? ( ポケットモンスター ベストウイッシュのオープニングテーマはベストウイッシュ!である)	(O) White - Yes. Spoiler: Click to show!
4	Game - Is Dageki the Judo Pokémon and Nageki the Karate Pokémon?(じゅうどポケモンがダゲキからてポケモンがナゲキである)	(X) Black - No. Nageki is the Judo Pokémon and Dageki is the Karate Pokémon. Spoiler: Click to show!

The black team won and received 10 points. The next portion of the quiz was Iwapalace's Letter Sorting Quiz (イワパレスの文字ならべかえクイズ）. 5 team members would have a letter placed on their back and the other team members would have to tell them which order they needed to go into to spell a Pokémon's name. They would crawl around until they got it right.


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Below are the Pokémon names that were rearranged in the quiz:

#	Letters	Answer
1	バモロルレ	Morobareru (モロバレル) Spoiler: Click to show!
2	クルスンラ	Lanculus (ランクルス) Spoiler: Click to show!
3	ャジツター	Tsutarja (ツタージャ) Spoiler: Click to show!
4	イニクビテ	Victini (ビクティニ) Spoiler: Click to show!
5	オキンラテ	Terrakion (テラキオン) Spoiler: Click to show!
6	ジマルュミ	Mijumaru (ミジュマル) Spoiler: Click to show!

White team ended up getting three done in the amount of time given and received 10 points. The next portion of the quiz was also a new event called Victini's V-Generate　Find the Mistake Obstacle Course Quiz (ビクティニのＶジェネレート障害物まちがいさがしクイズ). Participants would wear a helmet with a V shaped container that had balls in them. They would have to go through the obstacle course while trying not to drop the balls. The first part of the obstacle course was a balance beam they had to walk across, the second part was finding a candy ball in a flour pan, the third part was playing Hopscotch and the final part going under a bar while doing the limbo. For each ball that they had left at the end of the obstacle course, the team would get 1 second on the clock.


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The final part of the quiz was the 'Find the Mistake' part. Team white got 18 seconds to look at the original picture. Below is the original picture and the answers which shows the 10 differences. White team ended up winning the Caravan quiz.


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